{"id":663,"date":"2024-10-02T23:14:56","date_gmt":"2024-10-02T15:14:56","guid":{"rendered":"https:\/\/rayray.moe\/?p=663"},"modified":"2026-02-21T19:12:20","modified_gmt":"2026-02-21T11:12:20","slug":"pei-wei-ju-he-wu-de-lin-guang-xing-zhi-ji-suan","status":"publish","type":"post","link":"https:\/\/rayray.moe\/?p=663","title":{"rendered":"\u914d\u4f4d\u805a\u5408\u7269\u7684\u78f7\u5149\u6027\u8d28\u8ba1\u7b97"},"content":{"rendered":"<p>@tkaray CC-BY-NC 4.0<\/p>\n<p>\u53ea\u662f\u4e00\u70b9\u70b9\u8ba1\u7b97\u7ecf\u9a8c, \u4ec5\u4f9b\u53c2\u8003.<\/p>\n<h2><a id=\"%E6%A6%82%E8%BF%B0\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u6982\u8ff0<\/h2>\n<p>\u5173\u4e8e\u78f7\u5149\u6750\u6599\u7684\u57fa\u7840\u7406\u8bba, \u53ef\u4ee5\u53c2\u8003\u4ee5\u4e0b\u6587\u7ae0, \u6b64\u5904\u4e0d\u518d\u8d58\u8ff0\u4e86.<\/p>\n<p><em>Appl. Phys. Rev.<\/em> <strong>2022<\/strong>, <em>9<\/em>, 011304.<br \/>\n<em>WIREs Comput. Mol. Sci.<\/em> <strong>2012<\/strong>, <em>2<\/em>, 187\u2013203.<\/p>\n<p>\u548c\u6709\u673a\u78f7\u5149\u6750\u6599\u76f8\u6bd4, \u5bf9\u4e8e RTP-CPs \u548c RTP-MOFs \u7684\u8fc7\u7a0b\u7814\u7a76\u4f9d\u65e7\u6709\u4e00\u4e9b\u95ee\u9898, \u4e3b\u8981\u96c6\u4e2d\u5728\u4ee5\u4e0b\u51e0\u70b9:<\/p>\n<ul>\n<li>\u5f88\u591a\u4eba\u5c06\u957f\u65f6\u95f4\u4f59\u6656\u7684\u7a00\u571f\u91d1\u5c5e\u53d1\u5149\u5b9a\u4e49\u4e3a\u78f7\u5149, \u4f46\u6cdb\u6cdb\u5730\u79f0\u4e3a\u53d1\u5149 (luminescence) \u4f1a\u66f4\u4e3a\u8c28\u614e<\/li>\n<li>\u5e76\u6ca1\u6709\u641e\u6e05\u695a\u4f1a\u53d1\u78f7\u5149\u7684\u914d\u4f53\u8303\u56f4, \u6709\u4e00\u4e9b\u5df2\u6709\u7684\u6750\u6599\u53ef\u80fd\u5177\u6709\u6027\u8d28, \u4f46\u5e76\u672a\u62a5\u9053<\/li>\n<li>\u6784\u5efa\u7684\u8ba1\u7b97\u6a21\u578b\u8f83\u4e3a\u7b80\u5355, \u8ba1\u7b97\u5185\u5bb9\u8f83\u5c11, \u751a\u81f3\u53ea\u6709\u4e00\u4e2a\u914d\u4f53, \u4e0d\u80fd\u6709\u6548\u53cd\u6620\u5b9e\u9645\u8fc7\u7a0b<\/li>\n<li>\u5408\u9002\u7684\u8ba1\u7b97\u6a21\u578b\u539f\u5b50\u6570\u4e00\u822c\u90fd\u5f88\u5927, \u57fa\u672c\u53ea\u80fd\u7b97\u7684\u52a8DFT, \u8fd8\u53ea\u80fd\u57fa\u4e8e\u57fa\u6001\u6784\u578b<\/li>\n<\/ul>\n<p>\u5b9e\u9645\u4e0a\u8fd9\u4e2a\u65b9\u5411\u5df2\u7ecf\u9010\u6e10\u6ca1\u843d (\u7b11), \u4f46\u5c06\u4e0d\u540c\u7684\u5149\u5b66\u6027\u8d28\u7ed3\u5408\u8d77\u6765, \u6216\u8005\u62d3\u5c55\u6742\u5316\u78f7\u5149\u6750\u6599\u7684\u8303\u56f4, \u4f9d\u65e7\u8fd8\u80fd\u505a\u4e0a\u51e0\u5e74. \u4e3b\u8981\u7684\u95ee\u9898\u5728\u4e8e\u78f7\u5149\u6750\u6599\u5e94\u7528\u8303\u56f4\u5c0f, \u4e14\u5149\u8292\u88ab TADF \u6750\u6599\u63a9\u76d6\u4e86. \u597d\u5728\u8fd9\u4e8c\u8005\u7684\u8ba1\u7b97\u662f\u76f8\u901a\u7684. \u8fd9\u7bc7\u6587\u7ae0\u4e3b\u8981\u63d0\u4f9b\u4e00\u4e9b\u8ba1\u7b97\u4e0a\u7684\u53c2\u8003, \u5982\u679c\u6709\u540e\u7eed\u7684\u786e\u5b9a\u53ef\u884c\u7684\u5185\u5bb9\u4f1a\u9010\u6e10\u8865\u5145.<\/p>\n<h3><a id=\"%E5%8F%AF%E4%B8%BA%E4%B8%8E%E4%B8%8D%E5%8F%AF%E4%B8%BA\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u53ef\u4e3a\u4e0e\u4e0d\u53ef\u4e3a<\/h3>\n<p>\u5bf9\u4e8e\u914d\u4f4d\u805a\u5408\u7269\u7684\u78f7\u5149\u8ba1\u7b97\u80fd\u505a\u7684\u4e8b:<\/p>\n<ul>\n<li>\u83b7\u5f97\u6fc0\u53d1\u6001\u7684\u539f\u5b50\u7ed3\u6784, \u83b7\u5f97\u57fa\u6001\u4e0eT1\u6001\u6784\u578b\u4e0b\u6fc0\u53d1\u6001\u7684\u7535\u5b50\u7ed3\u6784<\/li>\n<li>\u5224\u65ad\u662f\u5426\u5b58\u5728\u6697\u6001\u4e0e\u53cd Kasha \u89c4\u5219\u7684\u53d1\u5c04<\/li>\n<li>\u786e\u5b9a\u7535\u5b50\u4e0e\u7a7a\u7a74\u5206\u5e03, \u5f97\u5230\u53d1\u5149\u8fc7\u7a0b\u7684\u8def\u5f84<\/li>\n<li>\u5224\u65ad ISC \u7684\u4e3b\u8981\u8def\u5f84<\/li>\n<li>\u83b7\u5f97\u78f7\u5149\u901f\u7387 (\u4e0d\u4e00\u5b9a\u9760\u8c31)<\/li>\n<\/ul>\n<p>\u5bf9\u4e8e\u914d\u4f4d\u805a\u5408\u7269\u7684\u78f7\u5149\u8ba1\u7b97, \u96be\u505a\u7684\u4e8b (\u80fd\u505a\u4f46\u5f88\u56f0\u96be\u6216\u4e0d\u9760\u8c31):<\/p>\n<ul>\n<li>\u5206\u6790\u5404\u79cd\u5404\u6837\u7684\u5916\u754c\u73af\u5883\u5bfc\u81f4\u7684\u78f7\u5149\u6027\u8d28\u53d8\u5316<\/li>\n<li>\u4fdd\u8bc1\u8ba1\u7b97\u7ed3\u679c\u548c\u5b9e\u9a8c (\u7d2b\u5916, \u6fc0\u53d1\u4e0e\u53d1\u5c04\u6ce2\u957f) \u80fd\u5bf9\u5e94<\/li>\n<li>\u83b7\u5f97T1\u4ee5\u5916\u7684\u6fc0\u53d1\u6001\u6784\u578b<\/li>\n<li>\u83b7\u5f97\u5b9e\u9645\u7684MECP\u70b9\u7ed3\u6784\u4e0e\u5bf9\u5e94\u7684ISC<\/li>\n<\/ul>\n<p>\u4e0d\u53ef\u80fd\u505a\u5230\u7684\u4e8b:<\/p>\n<ul>\n<li>\u83b7\u5f97\u548c\u5b9e\u9645\u7ed3\u679c\u5b8c\u5168\u4e00\u81f4\u7684\u6fc0\u53d1\u8fc7\u7a0b: \u53ea\u80fd\u505a\u53c2\u8003, \u5373\u4f7f\u662f\u5c0f\u6676\u80de\u4e5f\u5f88\u96be\u4fdd\u8bc1\u4e00\u5b9a\u548c\u6750\u6599\u4e00\u81f4, \u5927\u6676\u80de\u5c31\u66f4\u522b\u60f3\u4e86<\/li>\n<\/ul>\n<h3><a id=\"%E8%AE%A1%E7%AE%97%E8%BD%AF%E4%BB%B6\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u8ba1\u7b97\u8f6f\u4ef6:<\/h3>\n<p>ORCA \u662f\u6700\u503c\u5f97\u7528\u7684\u914d\u4f4d\u805a\u5408\u7269\u78f7\u5149\u8ba1\u7b97\u8f6f\u4ef6. \u652f\u6301QM\/MM, \u8ba1\u7b97\u901f\u5ea6\u5feb, \u597d\u6536\u655b, \u80fd\u7b97 SOCME, \u8fd8\u514d\u8d39. \u7f3a\u70b9\u662f\u5efa\u6a21\u9700\u8981\u5176\u4ed6\u8f6f\u4ef6\u8f85\u52a9, \u8fd9\u5c31\u516b\u4ed9\u8fc7\u6d77\u5404\u663e\u795e\u901a\u4e86. \u8bdd\u8bf4\u56de\u6765, \u53ea\u8981\u80fd\u8f93\u51fa\u56e2\u7c07\u5c31\u80fd\u5efa\u6a21, \u9009\u62e9\u4f60\u559c\u6b22\u7684 MOF \u753b\u56fe\u8f6f\u4ef6\u5c31\u591f\u4e86.<\/p>\n<p>Gaussian \u4e0d\u80fd\u7b97 SOCME, CP2K \u7684 SOCME \u5bf9\u914d\u4f4d\u805a\u5408\u7269\u78f7\u5149\u6765\u8bf4\u662f\u6446\u8bbe.<\/p>\n<p>\u78f7\u5149\u901f\u7387\u53ef\u4ee5\u8003\u8651 Dalton, \u4e5f\u53ef\u4ee5\u8003\u8651\u76f4\u63a5\u7528 ORCA \u7b97, \u4f46<strong>\u4f46\u51e1\u662f\u901f\u7387\u6570\u636e, \u90fd\u4e0d\u5982\u5b9e\u9a8c\u5206\u6790\u7ed3\u679c\u9760\u8c31.<\/strong><\/p>\n<h2><a id=\"%E4%B8%8D%E5%90%8C%E8%AE%A1%E7%AE%97%E7%AD%89%E7%BA%A7%E5%8F%8A%E6%93%8D%E4%BD%9C\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u4e0d\u540c\u8ba1\u7b97\u7b49\u7ea7\u53ca\u64cd\u4f5c<\/h2>\n<h3><a id=\"%E5%BB%BA%E6%A8%A1%E7%9A%84%E9%80%89%E6%8B%A9\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u5efa\u6a21\u7684\u9009\u62e9<\/h3>\n<p>\u53c2\u8003 Chem. Rev. 2020, 120, 8641\u22128715.<\/p>\n<ul>\n<li>\u9971\u548c\u6240\u6709\u80fd\u9971\u548c\u7684\u914d\u4f4d\u70b9, \u5426\u5219\u8ba1\u7b97\u7ed3\u679c\u5fc5\u4e0d\u51c6\u786e; \u5b9e\u5728\u4e0d\u884c\u5c31\u628a\u7fa7\u57fa\u5220\u6389.<\/li>\n<li>\u6240\u6709\u7684\u65e0\u5e8f\u90fd\u8981\u88ab\u5220\u6210\u5355\u5957.<\/li>\n<li>\u6ce8\u610f\u6c22\u539f\u5b50! MOF \u548c CP \u7684\u6676\u4f53\u6570\u636e\u90fd\u8981\u5c0f\u5fc3\u5904\u7406\u6c22\u7684\u95ee\u9898.<\/li>\n<li>\u7535\u8377\u4e0d\u8981\u662f\u8d1f\u503c, \u6700\u597d\u662f0\u6216\u8005\u8f83\u5c0f\u7684\u6b63\u503c, \u5426\u5219\u53ef\u80fd\u4f1a\u7b97\u5230\u5929\u8352\u5730\u8001\u4e5f\u5f97\u4e0d\u5230\u7ed3\u679c.<\/li>\n<li>\u91d1\u5c5e\u5fc5\u987b\u662f\u548c\u7ed3\u6784\u4e2d\u4e00\u81f4\u7684\u6ee1\u914d\u4f4d, \u5426\u5219\u5c31\u4f1a\u7b97\u6210MLCT\u8fc7\u7a0b\u4e86. \u5835\u5934\u53ef\u4ee5\u7528\u6c34\u6216\u7532\u9178. \u89c2\u5bdf\u7ed3\u679c, \u522b\u8ba9\u5835\u5934\u7684\u5206\u5b50\u53c2\u4e0e\u8fc7\u7a0b, \u8fd9\u6837\u80af\u5b9a\u662f\u4e0d\u9760\u8c31\u7684<\/li>\n<\/ul>\n<h3><a id=\"%E9%9A%8F%E4%BE%BF%E5%81%9A%E5%81%9A%E7%AE%97%E4%B8%AA%E9%85%8D%E4%BD%93\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u968f\u4fbf\u505a\u505a: \u7b97\u4e2a\u914d\u4f53<\/h3>\n<p>d10 \u8fc7\u6e21\u91d1\u5c5e\u548c\u4e3b\u65cf\u91d1\u5c5e\u7c07\u4e00\u822c\u662f\u4e0d\u4f1a\u53c2\u4e0e\u6fc0\u53d1\u8fc7\u7a0b\u7684, \u6240\u4ee5\u53ea\u662f\u7b97\u4e2a\u914d\u4f53\u4e5f\u6709\u4e2a\u7ed3\u679c. \u4f46\u662f\u8fd9\u6837\u5c31\u57fa\u672c\u53ea\u6709 HOMO, LUMO \u662f\u9760\u8c31\u7684, CT \u6001\u5c31\u65e0\u6cd5\u8868\u5f81\u4e86. \u7fa7\u9178\u914d\u4f53\u7528\u5e26\u6c22\u7684\u4e2d\u6027\u5206\u5b50\u7ed3\u6784, \u4e0d\u8981\u7528\u7fa7\u9178\u9634\u79bb\u5b50.<\/p>\n<h3><a id=\"%E6%89%A3%E4%B8%AA%E5%B0%8F%E5%9B%A2%E7%B0%87\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u6263\u4e2a\u5c0f\u56e2\u7c07<\/h3>\n<p>\u8fd9\u662f\u4e00\u822c\u53ef\u63a5\u53d7\u7684\u6700\u4f4e\u7b49\u7ea7. \u7ed3\u6784\u4f18\u5316\u8fc7\u7a0b\u4e2d\u539f\u5b50\u7684\u9501\u5b9a\u662f\u8fd9\u4e2a\u7b49\u7ea7\u6700\u9700\u8981\u6ce8\u610f\u7684\u4e8b. \u56e0\u4e3a\u6ca1\u6709\u4e86\u5916\u754c\u914d\u4f4d\u952e\u9650\u5236, \u4e0d\u52a0\u4f4d\u7f6e\u9650\u5236\u5f88\u5927\u6982\u7387\u4f1a\u6563\u67b6. \u53ef\u4ee5\u8003\u8651\u5148\u9650\u5236\u6240\u6709\u91d1\u5c5e\u539f\u5b50, \u5982\u679c\u4e0d\u884c\u5c31\u5e26\u7740\u4e0e\u91d1\u5c5e\u76f8\u8fde\u7684\u539f\u5b50\u9650\u5236, \u6700\u540e\u518d\u8003\u8651\u9650\u5236\u975e\u6c22\u539f\u5b50. \u5355\u6676\u7684\u6c22\u539f\u5b50\u4f4d\u7f6e\u662f\u4e0d\u51c6\u786e\u7684, \u81f3\u5c11\u4e5f\u8981\u5728\u7ed3\u6784\u4f18\u5316\u8fc7\u7a0b\u5c06\u6c22\u539f\u5b50\u7684\u4f4d\u7f6e\u8fdb\u884c\u4f18\u5316.<\/p>\n<p>\u56e2\u7c07\u7684\u5927\u5c0f\u4e0d\u8981\u8d85\u8fc7 300 \u539f\u5b50, \u5c3d\u53ef\u80fd\u7528\u6700\u5c0f\u4e0d\u5bf9\u79f0\u5355\u5143\u7684 1-2 \u500d (\u5982\u679c\u91cc\u9762\u6709\u4e00\u4e2a\u914d\u4f53\u7684\u8bdd).<\/p>\n<h3><a id=\"%E6%9B%B4%E5%A5%BD%E7%9A%84%E9%80%89%E6%8B%A9qmmm\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u66f4\u597d\u7684\u9009\u62e9: QM\/MM<\/h3>\n<p>\u5982\u679c\u80fd\u5728\u5c0f\u56e2\u7c07\u5916\u9644\u52a0\u6240\u6709\u73af\u5883\u5206\u5b50\u5c31\u662f\u4e00\u4e2a\u6bd4\u8f83\u5b8c\u5584\u7684\u8ba1\u7b97\u4e86. \u9700\u8981\u6ce8\u610f\u7684\u662f, high layer \u4f9d\u65e7\u9700\u8981\u7b26\u5408\u91d1\u5c5e\u6ee1\u914d\u4f4d\u7684\u8981\u6c42, \u4e5f\u5c31\u662f\u8bf4 high layer \u8981\u7528\u914d\u4f4d\u4f5c\u4e3a\u5916\u56f4, \u5305\u88f9\u4e2d\u95f4\u7684\u91d1\u5c5e.<\/p>\n<p>\u5efa\u6a21\u8fc7\u7a0b\u53ef\u4ee5\u8003\u8651\u5148\u786e\u5b9a\u5c0f\u56e2\u7c07\u4f5c\u4e3a high layer, \u7136\u540e\u586b\u5145\u5b83\u5468\u8fb9\u4e00\u5708\u7684\u91d1\u5c5e\u548c\u914d\u4f53, \u7136\u540e\u5904\u7406\u8fb9\u7f18\u88f8\u9732\u7684\u7fa7\u57fa (\u5220\u6389\u6bd4\u8f83\u597d), \u6700\u540e\u8ba1\u7b97\u7535\u8377. \u8981\u4fdd\u8bc1\u7535\u8377\u662f0\u6216\u8005\u6bd4\u8f83\u5c0f\u7684\u6b63\u503c. 100 \u539f\u5b50\u7684high layer \u4e00\u822c\u7528\u4e0d\u5230 1000 \u539f\u5b50\u5c31\u8db3\u591f\u5305\u88f9\u4e86, 300 \u539f\u5b50\u7684\u53ef\u80fd\u8981\u7528 2000-3000 \u539f\u5b50\u7684 low layer \u5305\u88f9.<\/p>\n<p>\u4e00\u4e2a\u5178\u578b\u7684 ORCA \u8f93\u5165\u6587\u4ef6\u4e3a:<\/p>\n<pre><code class=\"language-cpp\">! QM\/XTB PBE0 D4 def2-SVP def2\/J RIJCOSX tightSCF noautostart miniprint nopop\n! moread\n%moinp &quot;cluster-qmmm.gbw&quot;\n%basis \n  newGTO Zn &quot;def2-TZVP&quot; end\nend\n%qmmm\n   QMAtoms {0:64} end\n   ActiveAtoms {0:64} end\n   Charge_Total 0 # charge of the full system\n   Mult_Total 1 # mult. of the full system\nend\n%tddft\nnroots 20\nTDA true\ndosoc true\ntriplets true\nprintlevel 3\ntprint 1E-8\nend\n%maxcore  12000\n%pal nprocs  32 end\n* xyz 0 1\n(data)\n*\n<\/code><\/pre>\n<p>\u8fd9\u91cc\u4f7f\u7528\u4e86 QM\/xTB, low layer \u4f7f\u7528\u4e86 GFN2-xTB \u534a\u5b9a\u91cf\u65b9\u6cd5, \u5904\u7406 MOF \u6750\u6599\u5e94\u8be5\u662f\u8db3\u591f\u4e86.<\/p>\n<h3><a id=\"%E8%A1%A5%E5%85%85%E5%91%A8%E6%9C%9F%E6%80%A7%E8%AE%A1%E7%AE%97\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u8865\u5145\u5468\u671f\u6027\u8ba1\u7b97<\/h3>\n<p>\u5468\u671f\u6027\u8ba1\u7b97\u7684\u7535\u5b50\u7b49\u503c\u9762\u56fe, PDOS \u548c\u80fd\u5e26\u53ef\u4ee5\u4f5c\u4e3a\u8ba1\u7b97\u7684\u8865\u5145, \u7528\u4e8e\u9a8c\u8bc1\u81ea\u5df1\u6a21\u578b\u7ed3\u679c\u7684\u5408\u7406\u6027, \u503c\u5f97\u4e00\u8d77\u505a.<\/p>\n<h2><a id=\"%E5%85%B3%E4%BA%8E%E7%94%BB%E5%9B%BE\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u5173\u4e8e\u753b\u56fe<\/h2>\n<p>\u53c2\u8003 <a href=\"http:\/\/sobereva.com\/434\">\u4f7f\u7528Multiwfn\u505a\u7a7a\u7a74-\u7535\u5b50\u5206\u6790\u5168\u9762\u8003\u5bdf\u7535\u5b50\u6fc0\u53d1\u7279\u5f81<\/a><\/p>\n<h2><a id=\"%E7%A3%B7%E5%85%89%E5%8F%91%E5%B0%84%E9%80%9F%E7%8E%87%E8%AE%A1%E7%AE%97\" class=\"anchor\" aria-hidden=\"true\"><span class=\"octicon octicon-link\"><\/span><\/a>\u78f7\u5149\u53d1\u5c04\u901f\u7387\u8ba1\u7b97<\/h2>\n<p>\u8fd9\u90e8\u5206\u5c31\u53c2\u8003 ORCA Manual \u5427, \u4f46\u7b97\u518d\u591a\u4e5f\u6ca1\u6709\u7528\u91cf\u5b50\u4ea7\u7387\u548c\u53d1\u5c04\u901f\u7387\u5f97\u5230\u7684\u9760\u8c31.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>@tkaray CC-BY-NC 4.0 \u53ea\u662f\u4e00\u70b9\u70b9\u8ba1\u7b97\u7ecf\u9a8c, \u4ec5\u4f9b\u53c2 &hellip;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[30],"tags":[35],"class_list":["post-663","post","type-post","status-publish","format-standard","hentry","category-notes","tag-35"],"_links":{"self":[{"href":"https:\/\/rayray.moe\/index.php?rest_route=\/wp\/v2\/posts\/663","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/rayray.moe\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/rayray.moe\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/rayray.moe\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/rayray.moe\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=663"}],"version-history":[{"count":1,"href":"https:\/\/rayray.moe\/index.php?rest_route=\/wp\/v2\/posts\/663\/revisions"}],"predecessor-version":[{"id":664,"href":"https:\/\/rayray.moe\/index.php?rest_route=\/wp\/v2\/posts\/663\/revisions\/664"}],"wp:attachment":[{"href":"https:\/\/rayray.moe\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=663"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/rayray.moe\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=663"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/rayray.moe\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=663"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}